Processable, storable, isocyanatemodified polyesters



pound such as an amino alcohol United States Patent-O PROCESSABIJE, STQRABLELISDSYANATE- MODIFIED POLYESTERS No Drawing. Application Aug'ustZZ,

.Serial N0. 305,914

18 Claims. .(Cl. 260-75) This invention relates to synthetic polymeric materials and to methods for-preparing the same. More particularly, it relates .to organic diisocyanate-modified polyesters and polyester-amides :which possess elastomeric, rubber-like qualities and vto'improved methods for their preparation.

The modifying of linear polyesters and polyesterarnides with organic diisocyanates is ik-nown' in-the art. The polyesters are formed by the condensation of a dibasic carboxylic acid with a glycol. The polycsteramides are formed by the condensation of a dibasic carb-oxyl-ic-acid With a mixture .of a glycol and an amino bearing comand/or -adiamine. The condensation reaction proceeds withtheel-imination of water to yield a linear polyester or polyesterarnide which is usually viscous, syrupy, or wax-like at room temperature.

As is determined by the materials and amounts thereof used in its formation, the polyester or polyesteramide may contain terminal carboxyl, hydroxyl, or amino groups depending upon Whether an acid, a glycol, an amino alcohol, or a diamine was the last compound to react in the formation of the linear molecule. The polyester or polyesteramide is then lengthened further by the reaction between these terminal groups and an organic diisocyanate with the formation of what may be referred to as a chain-extended polymer. The linkages formed by the reaction of the terminal groups of the polyester with the diisocyan-ate are a urethane linkage ('1') H (Cl I) in the case of a terminal OH group, principally an amide linkage H H I in the case of a terminal COOH group,. and a substituted urea linkage N-,o-N) in the case of ,a terminal NH2 group. Since each of these linkages and, in the case of polyester-aunties, the amide groups, contain hydrogen available for reaction with additional diisocyanate, it is possible to cross link the chain-extended polymer at various points along its chain.

Depending upon many variables in their preparation, the diisocyanate-mod-ified polymers will vary considerably in their physical characteristics to include soft waxlike materials, el-astomeric rubber-like materialshard fiber-forming materials, tough leather-like materials, and hard infusible resinous materials. The rubber-like materials fit in between the soft wax-like materials and the tough leather-like materials, and will be discussed at greater length below.

Theorgan-ic diisocyanateemodified polyesters and, poly basic carboxylic acid and the other being a glycol. The particular polyesteramides, with which this invention is In the preparation of-the polyester or po'lyesteramide it cured '2 esteramides which possess-rubber-likeproperties have, up until the present invention, exhibited certain properties which make their use as synthetic rubbers impractical and undesirable. In particular, theknown rubber-like compositions have not possessed that degree of processibility required in the fabrication of. rubber orrubber-like products. In addition, the known compositions have or set up in'a relatively short time after their preparation, with the result that the uncured material cannot be stored for indefinite periods between the time it is prepared and the time it is used. It is therefore an object of this invention to provide a method for the preparation of highlyelastic organic diisocyanate-modifie d polyesters and polyesteramides which possess zprocessing qualities similar to those of uncured natural rubber and which may be-stored inthe uncured state over long periods of time without hardening or cur ing. It is a particular object of this invention to provide organic diisocyanate-modified polyesters and polyestenamides which possess not only processing and aging characteristics similar to those of uncured natural rubber but-also outstanding physical properties in the final vulcanized state. Still another object of this invention is to pro there are several critical limitations and requirements in the preparation of the polyester or polyesteram-ide itself, the chemical natur'eof the linkages'for-med between the diisocyanate and the terminal groups of the polyester or polyesteramide, and the type and amount of d-iisocyanate used-to chain-extend and possibly cro-ss link the poly ester or polyesterami-de, all of which limitations and requirements must be met in order to produce a rubber-like material which has the desired processing and aging properties in the uncured-state-and valuable physical properties in the final curedstate.

The unmodified polyester-is prepared in its simplest form from two bifunctional ingredients, one being a diconcerned, are those formed from the reaction of a dibasic carboxylic acid with a mixture comprising a glycol and an amino alcohol or a diamine. In addition, a'wide variety of complex polyesters and polyesteramides may be formed by the reaction of a plurality of acids, glycols, amino alcohols, or diarnines. In the preparation of polyesters, it is possible to use ester mixtures such as a physical mixture of ethylene adipate and 1,2-pr-opylene adipate as well as mixed esters such asthat resulting from the reaction of a mixture of. ethylene glycol and 1,2-propylen-e glycol with adipic acid. The reaction pro ceeds with the elimination of water to yield a long chain molecule containinga succession of'ester or ester-amide from an amino-alcohol,

Ro) from a glycol and a tdiamine. R in all instances denotes a divalent organic radicalsuch as a hydrocarbon radical.

is possible to. obtain-products of. varying molecular weight,

order to permit the subsequent modification with diiso cyanate to yield a processible, storable polymer. A convenient method of measuring the degree of polymeriza' tion of the polyester or polyesteramide is to determine the average number of carboxyl, hydroxyl, and amino groups in a given amount of the linear-extended polyester or polyesteramide; The acid number (milligrams of KOH per gram of polyester or p-olyesteramide using phenolphthalein as an indicator) is a measure of the number of terminal carboxyl groups in the polyester or polyesteramide. The hydroxyl number, which is a measure of the number of terminal hydroxyl and amino groups taken together, is determined by adding pyridine and acet-ic anhydride to the polyester or polyesteramide and titrat- -ing the acetic acid formed with KOH as described in Ind. Eng. Chem. Anal. Ed. 16, 541-49 and in Ind. Eng. Chem. Anal. Ed. 17, 394 (1945). The hydroxyl num' her is defined as milligrams of KOH per gram of polyester or polyesteramide. The sum' of the acid number and hydroxyl number, which will bereferred to as the reactive number, is an indication of the average number of terminal groups present in the polyester or polyesteramide which in turn is an indication of the numer of molecules in the mass and the degree of polymerization. A polyester or polyesteramide containing long chain molecules will have a relatively low reactive number, while a polyester or polyesteramide containing short-chain molecules will possess a higher reactive number.

According to the practice of the present invention, a rubber-like polymer is produced from a polyester or polyesteramide having a reactive number from 30 to 152. In preferred practice a polyester or polyesteramide having a reactive number from 50 to 65 is used. In addi tion, for the purposes of this invention, the acid numher in excess of 12 will produce diisocyanate-modified a maximum of 12, and preferably to a maximum of 5, since polyesters or polyester-amides having an acid numher in excess of 12 will produce diisocyanate-modified polymers which are too tough to process satisfactorily. The acid number is conveniently controlled by providing an approximate mol percent excess of glycol, amino alcohol, or diamine in the preparation of the polyester or polyesteramide.

The number of hydrogen-bearing amino groups in the polyesteramides is an additional critical feature applying to the preparation of rubber-like diisocyanate-modified polyesteramides. It has been found that polyesteramides produced from amino alcohols or diamines do not yield processible polymers when modified with certain diisocyanates if the number of -NH2 groups present in the reacting mixture exceeds of the total number of hydrogen-yielding groups present in the reacting mixture. This, in eliect, means that where amino alcohols are used, the maximum amount permissible is 60 mol percent, the other mol percent being a glycol. In the case of diamines, a maximum of 30 mol percent is permissible.

In the case of mixtures of glycols, amino alcohols, and

diarnines, the number of -NH2 groups present must be limited to a maximum of 30% of the total NH2 and --OH groups present.

According to the invention, it has also been discovered that the preparation of a processible, storable diisocyanate-modified polyester or polyesteramide involves a critical limitation in the particular diisocyanates and I amounts thereof which may be used. It has been set forth above that the nature of the modified polymer will depend upon the amount of diisocyanate used to chain-extend and cross-link the polyester. It has now been discovered that the production of a processible, storable rubber-like polymer depends upon the determination of the critical amounts of diisocyanate to be used. It has also been discovered that this cirtical amount of diisocyanate depends upon which specific diisocyanate is employed to modify the polyester or polyesteram-ide.

The particular diisocyanates with which this invention is concerned are the tolylene diisocyanates such as 2,5- tolylene diisocyanate and particularly the meta tolylene diisocyanates, such as 2,6-t'olylene diisocyanate; 3,5-tolylene diisocyanate and preferably 2,4-tolylene diisocyanate or mixtures thereof such as mixtures of the 2,4- and 2,6- isomers. For the purposes of this invention these diisocyanates must be used in an amount ranging from 0.85 to 1.10 mols per mol of polyester or polyesteramide. A preferred range is from .90 to 1.00 mol of diisocyanate per mol of polyester or polyesteramide while optimum results are obtained in a range from 0.94 to 1.00. Amounts smaller than 0.85 mol will produce soft, sticky polymers which will not process satisfactorily in the usual rubber fabricating operations. Amounts greater than 1.10 mols produce tough polymers which will not process satisfactorily and which will harden or cure upon aging. It is possible to use a mixture of tolylene diisocyanates in the preparation of the rubber-like polyesters and polyesteramides so long as the total amount of diisocyanate used falls within the range indicated. While certain other diisocyanates will not produce the desired results if used in an amount covered by the critical range specified, it is to be understood that the tolylene diisocyanates are not necessarily the only diisocyanates which are operative for the purposes of this invention but rather represent those which produce the desired results when employed in an amount falling within the critical range indicated.

After the processible storable polymer has been formed, it is prepared for curing by adding more diisocyanate or other conventional curing materials such as alkyl ethers of hexamethylol melamine with a 2,4-dihalo naphthol as accelerator. Polyisocyanates, such as 4,4,4"-triisocyanto triphenyl methane, 1,3,5-triisocyanto benzene, and 2,4,6- triisocyanto toluene, may also be used to effect a cure. Any organic diisocyanate, polyisocyanate or mixtures of diisocyanates, polyisocyanates', or both may be added in this step. It may be the same or a different diisocyanate than that used in the formation of the processible polymer, or it may be a diisocyanate other than those listed. A convenient method of adding the tolylene diisocyanate to be used either in the formation of the chain-extended polymer or as a curing agent, is in the form of one of its dimers such as the dimer of 2,4-tolylene diisocyanate of the following formula:

-NCO equivalents, including that added in the formation of the processible polymer, ranging from 2.80 to 3.20

equivalents of --'NCO per mole of polyester or poly esteramide. Smaller amounts of polyisocyanate added to cure the polymer will result in an under cured product. The use of greater amounts is a Waste of material with no improved properties in thecured product, and in some cases produces a cured polymer having properties more resinous than rubber-like.

If a triisocyanate or "tetraisocyan'ate is used to cited a cure, not as much material, on a mol basin-need be used since the curing or cross-linking of the linear molecules depends upon the NCO groups present in the curing agent. For example, if 0.40 mol of a diisocyanate gives a satisfactory cure of a diisocyanatemodified polyester or polyesteramide, the use of approximately 0.20 mol of a tetraisocyanate will result in a similar state of cure.

The actual curing of the polymer is accomplished by methods familiar to those skilled in the'art. The time and temperature required to effect the best cure for any particular polymer will, of course, Vary as, is the case withconventional natural rubber compounds. The cure, for best results, shouldbe accomplished by the use of dry heat since exposureof the pollymer to hot water or steam results in a partial degenerationof thecuredmaterial.

The following-examples, in which parts are by weight, are illustrative of the preparation of thep'olye'ster and polyesteramides and of the diisocyanate-modified polyester and polyesteramidesaccording to the teachings of this invention.

EXAMPLE 1 Preparation of a typical' polyester Adipic acid (3515 parts) --was placed inaS liter, '3- necked flask fitted with a stirrer, thermo-couple well, gas inlet tube, distilling head, and condenser. To the acid were added 1064 parts of ethylene glycol and 869 parts of propylene'l,2 glycol. Themolar ratio ofdi-basic acid to glycol is 1:1.19. The-mixture washeated to 130-160" C. until most of the water had distilled 01f. The temperature was then gradually raised to 200 C., the pressure being gradually reduced to 20 mm. and nitrogen being bubbled through the melt. After 23 /2 hours :1 soft white Waxy solid Was-obtained. Determinations showed the acid number to be 3.5 and the hydroxyl number to be 58.6.

EXAMPLE 2 Preparation ofthe diisocyanate-mo'dified polymer A'quantity of polyester was'prepared from adipic acid, ethylene glycol, and propylene 1,2 glycol according to the general method and in substantially the same ratios as shown in Example 1. This polyester had an acid-number of 3.1 and a hydroxyl number of 55.6. After heating 200 parts of this polyester to 120 C. in an-iron kettle, 2,4-tolylene diisocyanate (20.11 parts of 99.7% purity or 1.10 mols of diisocyanate per mol of polyester) was added. After 15 minutes of mixing, the material was poured into a waxed aluminum tray and baked for 8 hours at 120 C. The resulting-polymer had excellent processing characteristics on a rubber mill.

sheets cured for 60 minutes at 300 F. showed'the following physical properties:

Tensile 2600 pounds per square inch. Elongation 710%.

300% modulus 300 pounds per squareinch.

Table I shown below tabulates selected examples of polyesters and diisocyanate-modified polyesters which were prepared according to the practices of this invention and according to the general procedure outlined in Examples 1 and 2.

PolyesterA-SO mol percent ethyleneglycol, 20 mol'percent propylene 1,2-glycol, adipic acid. I

Diisocyanate A2,4-tolylene dilsocyanate.

1 Mols of diisoeyanate'per mol of polyester.

The rating indicated for each polymer is 'basedupon its behavior on a rubber mill in relation to its .processibility on the mill and on other rubber fabricating equipment. The polymers described in Table I' have been found to ageat room temperature'for longperiods of time withlittle or no apparent change in their'pr'o'cessing characteristics.

In addition to the specific materials vshown i'n'th e experimental-exarnples, a varie'ty of other acids, glycols, amino alcoholsand diamines may 'be-used. Any dibasic carboxylic acid containingat least '3 carbon atoms, and preferably those whose carboxyl groups are attached to'terminal carbons, may be usedto form the polyester or polyesteramide, including succinic, glutaric, adipic, pimelic,-suberic, azelaic, sebacic, malonic, brassylic, tartaric, maleic, malic, fumaric, dilinoleic, thiodibutyric, diphenic, isophthalic, terephthalic, hexahydroterephthalic, p-phenylene diacetic, dihydromuconic, and B-methyladipic acids. Forbest'results'the unsaturated acids should be usedin mixture with a saturated acid'in an amount not to exceed 5 mol'percent of the mixture. The'presence of a small amountof unsaturation in the polyester 01' polyesteramide is often desirable if cheaper curing orcrosslinking a'g'ents'such as for example, sulfur, benzoyl peroxide, or tertiary butyl hydroperoxide are to be used Higher degrees of unsaturation in the polyester or polyesteramideresult in cured polymers which do not have the outstanding physical. properties possessed by the polymers produced from polyesters or polyesteramides containing no unsaturation or a relatively small amount of unsaturation.

Any glycol may be used in the formation'of the polyesters or polyesteramides including ethylene, propylene 1,2, propylene 1,3, diethylene, triethylene, tetramethylene, pentamethylene, hexamethylene, decamethylene, dodecamethylene, and NgN-diethanolaniline.

Any amino alcohol havingat least one hydrogen atom attached to the amino nitrogen atom may be employed including ethanolamine, 3-amino-propanol, 4-amino-butanol, 6- amino-hexanol, IO-amino-decanol.

Examples of the diamines which may be used are a ethylene, propylene 1,2, propylene 1,3, tetramethylene 1,4, hexamethylene 1,6, decamethylene 1,10, the tolylene diamines, piperazine,isopropylaminopropyl amine, 4,4- diamino diphenyl methane, and 3,3 dianiin'o dipropyl ether.

In addition to the examples already shown, listed below are the reactants which are used to form particular polyesters and polyesteramides which when modified with diisocyanate according to the practice of this invention will produce processible, storable polymers.

propylene glycol 7. Ethylene glycol (80 mol percent), glycerine monoethyl ether (20 mol percent) plus adipic acid.

8. Ethylene glycol (80 mol percent), butylene glycol 1,4 (20 mol percent) plus adipic acid.

9. Ethylene glycol (80 mol percent), propylene glycol 1,3 (20 mol percent) plus adipic acid.

10. Ethylene glycol (80 mol percent), (20 mol percent) plus adipic acid.

11. Ethylene glycol (80 mol percent), glycerine monoisopropyl ether (20 mol percent) plus adipic acid.

12. Ethylene glycol (80 mol percent), propylene glycol 1,2 (from 18 to mol percent), ethanol amine (from 2 to 15 mol percent) plus adipic acid.

13. Ethylene glycol (80 mol percent), propylene glycol 1,2 (20 mol percent) plus maleic acid (from 3 to 6 mol percent), adipic acid (from 97 to 94 mol percent).

14. Ethylene glycol (80 mol percent), propylene glycol 1,2 (from 19 to 17 mol percent), piperazine (from 1 to 3 mol percent) plus adipic acid.

15. Ethylene glycol (80 mol percent), propylene glycol 1,2 (from 18 to 5 mol percent), dihydroxyethyl aniline (from 2 to 15 mol percent) plus adipic acid.

16. Ethylene glycol (80 mol percent), diethylene glycol 20 mol percent) plus adipic acid.

17. Ethylene glycol (from 90 to mol percent), propylene glycol, 1,2 (from 10 to 90 mol percent) plus adipic acid.

18. Ethylene glycol pylene glycol 1,2 azelaic acid.

pentane diol 1,5

(from 90 to 10 mol percent), pro- (from 10 to 90 mol percent) plus Any of the above materials will produce polyesters or polyesteramide which when prepared and treated according to the practice of this invention will yield processible, storable polymers after reaction with any of the tolylene diisocyanates.

Of particular interest are the rubber-like polymers resulting from (1) polyethylene adipate modified by at least one tolylene diisocyanate, (2) polypropylene 1,2 adipate modified by at least one tolylene diisocyanate, (3) polyethylene (80 mol percent) propylene 1,2 (20 mol percent) adipate modified by at least one tolylene diisocyanate, (4) polyethylene (80 mol percent) propylene 1,2 (20 mol percent) azelate modified by at least one tolylene diisocyanate, and (5) polyethylene (80 mol percent) propylene 1,2 (from 19 to 17 mol percent) piperazine (from 1 to 3 mol percent) adipate modified by at least one tolylene diisocyanate.

The elastomeric polymers prepared according to the practices of this invention are, in general, useful in those applications where natural rubber or rubber-like materials are used. In particular they may be used in tires, belts, hose, sheet packing, gaskets, molded goods, floor mats, dipped goods, sheeting, tank lining, soles, heels, covered rolls, and other mechanical and industrial goods.

This application is a continuation-in-part of our copending application, Serial Number 170,056 filed June 23, 1950, now abandoned.

While certain representative embodiments and details have been shown for the purpose of illustrating the invention, it will be apparent to those skilled in this art that various changes and modifications may be made therein without departing from the spirit or scope of the invention.

We claim:

1. The processable, storable elastomeric reaction product of (A) a material prepared from bifunctional ingredients including at least one dibasic carboxylic acid containing at least 3 carbon atoms and at least one complementary bifunctional reactant in which the functional groups are selected from the class consisting of the hydroxyl group and the hydrogen-bearing amino groups, the hydrogen-bearing amino groups being present in an amount not to exceed 30% of the total functional groups of said complementary bifunctional reactant, said material having an acid number from. 0 to 12 and the sum from 30 to 152, and

of the hydroxyl and acid numbers of said material being from 30 to 152, and (B) at least one tolylene diisocyanate used in an amount ranging from 0.85 to 1.10 mols per mol of said material.

2. The processable, storable elastomeric reaction product of (A) a material prepared from bifunctional ingredients including at least one dibasic carboxylic acid containing at least 3 carbon atoms and at least one complementary bifunctional reactant in which the functional groups are selected from the class consisting of the hydroxyl group and the hydrogen-bearing amino groups, the hydrogen-bearing amino groups being present in an amount not to exceed 30% of the total functional groups of said complementary bifunctional reactant, said material having an acid number from O to 12 and the sum of the hydroxyl and acid numbers of said material being (B) at least one meta tolylene diisocyanate used in an amount ranging from 0.85 to 1.10 mols per mol of said material.

3. The processable, storable elastomeric reaction product defined by claim 1 in which the complementary bifunctional reactant is a glycol.

4. The processable, storable elastomeric reaction product defined by claim 3 in which (A) is a polyester prepared frorn adipic acid, ethylene glycol and propylene glycol.

5. The processable, storable elastomeric reaction product defined by claim 4 in which the polyester is prepared from approximately mol percent of ethylene glycol, approximately 20 mol percent of propylene glycol, and adipic acid.

6. The processable, storable elastomeric reaction product defined by claim 5 in which the polyester has an acid number from 0 to- 12 and a hydroxyl number such that the sum of the acid number and hydroxyl number is from 50 to 65, and in which the diisocyanate is used in an amount ranging from 0.90 to 1.00 mol per mol of polyester.

7. The processable, storable elastomeric reaction product defined by claim 1 in which the diisocyanate is used in an amount ranging from 0.90 to 1.00 mol per mol of said material.

8. The processable, storable elastomeric reaction product defined by claim 7 in which the diisocyanate is used inan amount ranging from 0.94 to 1.00 mol per mol of said material.

9. The processable, storable elastomeric reaction product defined by claim 1 in which (A) is prepared from azelaic acid.

10. The process for making a processable, storable elastomeric reaction product which comprises reacting (A) a material prepared from bifunctional ingredients including at least one dibasic carboxylic acid containing at least 3 carbon atoms and at least one complementary bifunctional reactant in which the functional groups are selected from the class consisting of the hydroxyl group and the hydrogen-bearing amino groups, the hydrogenbearing amino groups being present in an amount not to exceed 30% of the total functional groups of said complementary bifunctional reactant, said material having an acid number from 0 to 12 and the sum of the hydroxyl and acid numbers of said material being from 30 to 152 with (B) at least one tolylene diisocyanate used in an amount ranging from 0.85 to 1.10 mols per mol of said material.

11. The process defined by claim 10 in which the complementary bifunctional reactant is a glycol.

12. The process defined by claim 11 in which (A) is a polyester prepared from ethylene glycol, propylene glycol, and adipic acid. I

13. The process defined by claim 12 in which the polyester has an acid number from 0 to 12 and a hydroxyl number such that the sum of the acid number and hydroxyl number is from 50 to 65, and in which the diisocyanate is used in an amount ranging from 0.90 to 1.00 mol per mol of polyester.

14. The process defined by claim 10in which the diisocyanate is used in an amount ranging from 0.90 to 1.00 mol per mol of said material.

15. The process defined by claim 14 in which the diisocyanate is used in an amount ranging from 0.94 to 1.00 mol per mol of said material.

16. The process for making a cured elastomeric composition which comprises reacting the product prepared according to the process defined by claim 10 with a sufiicient amount of at least one polyisocyanate to bring the total number of NCO equivalents used in the preparation of said cured composition to from 2.80 to 3.20 equivalents of NCO per mol of said material.

17. The process for making a cured elastomeric diisocyanate-modified material which comprises reacting the product prepared according to the process defined by claim 14 with a sufficient amount of at least one polyisocyanate to bring the total number of --NCO equivalents used in the preparation of said cured composition to from 2.8 to 3.20 equivalents per mol of said material.

18. The process for making a cured elastomeric diisocyauate-modified polyester which comprises reacting the reaction product prepared according to the process defined by claim 15 with a suificient amount of at least one polyisocyanate to bring the total number of -NCO equivalents reacted with the polyester to from 2.8 to 3.2 equivalents per mol of polyester.

References Cited in the file of this patent UNITED STATES PATENTS 2,621,166 Schmidt et a1. Dec. 9, 1952 2,625,531 Seeger Jan. 13, 1953 2,625,532 Seeger Jan. 13, 1953 

1. THE PROCESSABLE, STORABLE ELASTOMERIC REACTION PRODUCT OF (A) A MATERIAL PREPARED FROM BIFUNCTIONAL INGREDIENTS INCLUDING AT LEAST ONE DIBASIC CARBOXYLIC ACID CONTAINING AT LEAST 3 CARBON ATOMS AND AT LEAST ONE COMPLEMENTARY BIFUNCTIONAL REACTANT IN WHICH THE FUNCTIONAL GROUPS ARE SELECTED FROM THE CLASS CONSISTING OF THE HYDROXYL GROUP AND THE HYDROGEN-BEARING AMINO GROUPS, THE HYDROGEN-BEARING AMINO GROUPS BEING PRESENT IN AN AMOUNT NOT TO EXCEED 30% OF THE TOTAL FUNCTIONAL GROUPS OF SAID COMPLEMENTARY BIFUNCTIONAL REACTANT, SAID MATERIAL HAVING AN ACID NUMBER FROM 0 TO 12 AND THE SUM OF THE HYDROXYL AND ACID NUMBERS OF SAID MATERIAL BEING FROM 30 152, AND (B) AT LEAST ONE TOLYLENE DIISOCYANATE USED IN AN AMOUNT RANGING FROM 0.85 TO 1.10 MOLS PER MOL OF SAID MATERIAL. 